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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 577 (1989), S. 255-262 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Synthese und Eigenschaften des orthometallierten Komplexes Rh{P(OPh)3}3{P(OC6H4)(OPH)2}Der orthometallierte Komplex Rh{P(OPh)3}3{P(OC6H4)(OPh)2} (1) wurde durch die Reaktion von [Rh(OCH3)(cod)]2 und P(OPh)3 erhalten. Auf der Basis der 31P-NMR- und UV-VIS-Daten wird die alternative Struktur  -  Rh{P(OPh)3}3{P(O)(OPh)2} (2)  -  diskutiert. Sowohl der Bildungsprozeß der Verbindung wie ihr reaktives Verhalten erlauben sie als den orthometallierten Komplex (1) anzusehen.
    Notes: The orthometallated complex formulated as Rh{P(OPh)3}3{P(OC6H4)(OPh)2} (1) was obtained in the reaction between [Rh(OCH3)(cod)]2 and P(OPh)3. Based on the 31PNMR and UV-VIS results the alternative structure of that compound  -  Rh{P(OPh)3}3{P(O)(OPh)2} (2)  -  was discussed. Both  -  the formation process of that compound and its reactivity allow to regard it as the orthometallated complex (1).
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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