ISSN:
0044-2313
Keywords:
Carbonyl coordination compounds
;
α-Functionalized 2-methyl phenylphosphines
;
W(CO)5 shift
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
α-Functionalized 2-Methyl Phenylphosphines, 2-(HE—CH2)—C6H4—PH2 (E = O, NR, PH) II. Coordination Behaviour with Metal Carbonyles of Cr, Mo, WThe preparation of different carbonyl substituted coordination compounds (M: Cr, Mo, W) of the phosphines 2-(HE—CH2)C6H4—PH2 (E = O, NPh, PH) is described. In one case, after deprotonation of a PH2 group a phosphine/phosphide migration of a W(CO)5 fragment is detected.
Notes:
Von drei α-funktionellen Methylphenylphosphanen 2-(HE—CH2)C6H4—PH2 (E = O, NPh, PH) werden Carbonylkomplexe der Metalle Cr, Mo, W beschrieben. In einem Fall wird nach Metallierung die Wanderung eines phosphano-koordinierten W(CO)5-Fragmentes an ein bereits W(CO)5-koordiniertes Phosphid beobachtet.
Additional Material:
4 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19956210928
