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Methyl substituent effects on the dissociation energies of Si—X bonds (1991)

Luo, Yu-Ran ; Pacey, Philip D.

Chichester : Wiley-Blackwell

Journal of Physical Organic Chemistry 4 (1991), S. 562-565

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ISSN: 0894-3230

Keywords: Organic Chemistry ; Physical Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: Empirical expressions are obtained for bond dissociation energies (BDEs) of alkylsilanes and their derivatives. It is pointed out that the sensitivity of the BDEs of Si—X bonds to methyl substitution depends on the electronegativity of the substituent X. When X is an atom or group with low or moderate electronegativity, the Si—X BDE is insensitive to methyl substitution, but when X is a halogen atom or OH, the Si—X BDEs increase with increasing methyl substitution.

Additional Material: 1 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/poc.610040906

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