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Direct observation of the ylides formed upon reaction of cyclopentadienylidene with acetic anhydride, dimethyl carbonate, ethyl acetate and acetone (1996)

Platz, Matthew S. ; Olson, David R.

Chichester : Wiley-Blackwell

Journal of Physical Organic Chemistry 9 (1996), S. 689-694

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ISSN: 0894-3230

Keywords: Chemistry ; Theoretical, Physical and Computational Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: Cyclopentadienylidene was studied by laser flash photolysis (LFP) techniques. LFP of diazocyclopentadiene in acetic anhydride, acetaldehyde, acetone, dimethyl carbonate, ethyl acetate, acetonitrile, dimethyl sulfide and pyridine produces UV-visible active ylides. The first reports of the direct detection of carbene - anhydride, carbene-aldehyde, carbene-amide and carbene-carbonate ylides are presented. The spectra and the lifetimes of these ylides are reported.

Additional Material: 11 Ill.

Type of Medium: Electronic Resource

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