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Kinetic study of the reactions of O-alkylisoureas with OH-acidic compoundsDedicated to Professor E. Vowinkel on the occasion of his 70th birthday. (1998)

Jaeger, Rolf

Chichester : Wiley-Blackwell

Journal of Physical Organic Chemistry 11 (1998), S. 47-53

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ISSN: 0894-3230

Keywords: N,N′-dicyclohexyl-O-(1-methylheptyl)isourea ; OH-acidic compounds ; acetic acid ; kinetics ; mechanisms ; Chemistry ; Theoretical, Physical and Computational Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: Kinetic investigations on the reaction of N,N′-dicyclohexyl-O-(1-methylheptyl)isourea with acetic acid are described. The conversion proceeds partly through the intermediacy of a methylheptylcarbenium ion. However, in dilute solution an SN2 mechanism prevails. The results are discussed in terms of the simultaneous existence of two discrete mechanisms. © 1998 John Wiley & Sons, Ltd.

Additional Material: 6 Ill.

Type of Medium: Electronic Resource

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