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Oxidation of allyl alcohol by alkaline periodate in the presence of micro amounts of palladium(II) (1998)

Hiremath, Gouri A. ; Timmanagoudar, Prakash L. ; Nandibewoor, Sharanappa T.

Chichester : Wiley-Blackwell

Journal of Physical Organic Chemistry 11 (1998), S. 31-35

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ISSN: 0894-3230

Keywords: allyl alcohol ; oxidation ; alkaline periodate ; palladium(II) catalyst ; Chemistry ; Theoretical, Physical and Computational Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: The oxidation of allyl alcohol by alkaline species of periodate, H2IO63-, was found to be catalysed by micro amounts of Pd(II) in 0.2 mol dm-3 alkali solution. The active species of the catalyst was found to be PdCl+. A mechanism involving the interaction of the catalyst and substrate in prior equilibria leading to the formation of a π-complex is proposed and the rate is derived. © 1998 John Wiley & Sons, Ltd.

Additional Material: 3 Ill.

Type of Medium: Electronic Resource

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