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Correlation of the rates of solvolysis of the N,N-diphenylcarbamoylpyridinium ion (1998)

Kevill, Dennis N. ; Bond, Michael W. ; D'Souza, Malcolm J.

Chichester : Wiley-Blackwell

Journal of Physical Organic Chemistry 11 (1998), S. 273-276

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ISSN: 0894-3230

Keywords: N,N-diphenylcarbamoylpyridinium ion ; solvolysis ; Chemistry ; Theoretical, Physical and Computational Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: Solvolyses of the N,N-diphenylcarbamoylpyridinium ion are subject to specific and/or general base catalysis, which can be eliminated by addition of perchloric acid or increased, especially in fluoroalcohol-containing solvents, by addition of pyridine. The uncatalyzed solvolyses in aqueous methanol and aqueous ethanol involve a weakly nucleophilically assisted (l = 0.22) heterolysis and the solvolyses in the pure alcohols are anomalously slow. © 1998 John Wiley & Sons, Ltd.

Additional Material: 2 Tab.

Type of Medium: Electronic Resource

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