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Digitale Medien

Drugs for chiral discrimination: Non-coded amino acids and dipeptides by asymmetric hydrogenation (1998)

Kreuzfeld, H.-J. ; Döbler, Chr. ; Schmidt, U. ; [weitere]

New York, NY [u.a.] : Wiley-Blackwell

Chirality 10 (1998), S. 535-539

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Details

ISSN: 0899-0042

Schlagwort(e): asymmetric hydrogenation ; non-coded amino acids ; enantioselectivity ; dipeptides ; diastereoselectivity ; Chemistry ; Organic Chemistry

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie

Notizen: The enantiomers of Propranolol, Pindolol, and Carazolol, well-known β-blockers, have been used to prepare cationic aminophosphine phosphinite rhodium complexes. Propraphos-Rh and Pindophos-Rh are very efficient catalysts in the asymmetric hydrogenation of N-Boc-protected unusual dehydroamino acid derivatives. Carazolol-Rh is less suitable in both activity and enantioselectivity. Under the same conditions, N-Boc-protected dehydrodipeptides are hydrogenated with diastereoselectivities between 70 and 90% de. Chirality 10:535-539, 1998. © 1998 Wiley-Liss, Inc.

Zusätzliches Material: 1 Ill.

Materialart: Digitale Medien

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