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  • 1
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 11 (1973), S. 2111-2126 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Solubility of monomer in the polymer was strongly affected by ionic strength; with increasing ionic strength, solubility was found to increase. At constant temperature, this was entirely due to the decrease in interfacial tension, as the condensation of surfactant proceeded at the interface. The temperature affected both the polymer-solvent interaction parameter as well as the interfacial tension. These are the two parameters on which solubility depends. The variations of interfacial tension with temperature was found to be complex, but entirely dependent on the entropic consideration of adsorption. The polymer-solvent interaction parameter-inverse temperature dependence was found to be linear, as expected.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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