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On the mechanism of the polymerization of poly(vinyl chloride) (1978)

Caraculacu, A. ; Buruiană, E. C. ; Robilă, Gabriela

New York : Wiley-Blackwell

Journal of Polymer Science: Polymer Chemistry Edition 16 (1978), S. 2741-2745

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Details

ISSN: 0360-6376

Keywords: Physics ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The polymerization of poly(vinyl chloride) (PVC), head-to-head macroradical plays an essential role in the formation of branches and the appearance of interruption processes that lead to labile unsaturated end groups. A reaction mechanism is suggested to explain these processes and the method of formation of internal double bonds as a result of transfer to polymer. The transfer to monomer can occur only by atom acceptance by the macroradical and not by the monomer giving up an atom.

Additional Material: 1 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1978.170161102

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