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Photoinitiated cationic polymerization by triarylselenonium salts (1979)

Crivello, J. V. ; Lam, J. H. W.

New York : Wiley-Blackwell

Journal of Polymer Science: Polymer Chemistry Edition 17 (1979), S. 1047-1057

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ISSN: 0360-6376

Keywords: Physics ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Triarylselenonium salts with complex metal halide anions such as BF4-, AsF6-, and SbF6- have been prepared and have been shown to be efficient photoinitiators of cationic polymerization. The photolysis rates of these compounds were studied and their quantum yields of photolysis were reported. Use of specific triarylselenonium salts in the polymerizations of cyclohexene oxide, epichlorohydrin, and 2-chloroethyl vinyl ether are described.

Additional Material: 7 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1979.170170410

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