Digitale Medien
New York
:
Wiley-Blackwell
Journal of Polymer Science: Polymer Chemistry Edition
19 (1981), S. 1841-1846
ISSN:
0360-6376
Schlagwort(e):
Physics
;
Polymer and Materials Science
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
The rates of reaction of acid chloride groups with nitrophenol groups were measured with the groups attached to polymer chains. The average degree of substitution was kept low, near to one or less groups per chain. It was found that the interpolymer reaction rates decreased several fold in dilute solution for high polymers compared with the rates in more concentrated solutions or with those for low-molecular-weight polymers. The results were compared with the models proposed by Morawetz and the effect was of the predicted magnitude. The results also confirmed Morawetz' prediction that smaller effects could be expected for terminally substituted than for randomly substituted polymers.
Zusätzliches Material:
5 Tab.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/pol.1981.170190723
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