ISSN:
0360-6376
Keywords:
Physics
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Polysalicylide, a condensation product of acetylsalicylic acid, was irradiated with 60Co-γ-rays. Viscosity, end-group analysis, and ultraviolet (UV) spectral measurement technique, and electrical conductivity were used to study the changes that occurred during γ-radiolysis. It was observed that polysalicylide undergoes chain scission caused by weak links. The enthalpy of fusion is 16.0 and 13.4KJ/mol-1 repeat units of polysalicylide in air and N2, respectively. The indirect effective band gap decreased and electrical conductivity increased after irradiation.
Additional Material:
10 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pol.1984.170220322