ISSN:
0360-6376
Keywords:
Physics
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The copolymerizations of acrylamide (AM) with N-(1,1-dimethyl-3-oxybutyl)acrylamide (DAAM) and with N,N-dimethylacrylamide (DMAM) have been studied. The values of r1,r2 have been determined to be 0.75 for the AM-DAAM pair and 0.86 for the AM-DMAM pair. The molecular weights of the copolymers were found to decrease with an increase in the feed composition of DAAM or DMAM. The microstructure was predicted for a wide range of feed compositions through a knowledge of reactivity ratios. These model structures are utilized for assessment of structure/dilute solution relationships reported in a subsequent paper in this series.
Additional Material:
6 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pol.1984.170221202
