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A poly(ethylene oxide)-mercuric chloride complex (1964)

Blumberg, Avrom A. ; Pollack, Sidney S. ; Hoeve, C. A. J.

New York : Wiley-Blackwell

Journal of Polymer Science Part A: General Papers 2 (1964), S. 2499-2502

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Details

ISSN: 0449-2951

Keywords: Chemistry ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: Oriented poly(ethylene oxide) fibers form a complex with mercuric chloride, with the empirical formula (CH2CH2O)4·HgCl2. Tentatively the unit cell of the complex is orthorhombic with dimensions 13.5, 17.1, and 11.6 A. (c, the fiber axis). In spite of a major change in the unit cell, fiber orientation is maintained. The infrared spectrum of the complex is more detailed than that of the polymer alone, a fact consistent with a change from trans to gauche state of one O—C bond.

Additional Material: 1 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1964.100020601

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