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Effect of polydispersity on liquid-liquid phase equilibrium (1967)

Baysal, B. M. ; Stockmayer, W. H.

New York : Wiley-Blackwell

Journal of Polymer Science Part A-2: Polymer Physics 5 (1967), S. 315-322

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ISSN: 0449-2978

Keywords: Physics ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: The effect of polydispersity on liquid-liquid phase equilibrium in systems containing polymer, solvent, and nonsolvent is investigated numerically in the Flory-Huggins approximation for several special cases. The resulting phase diagrams indicate that, except in the immediate vicinity of the critical region, the degree of swelling of a polymer precipitate phase with a given number-average molecular weight is essentially independent of polydispersity.

Additional Material: 3 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1967.160050207

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