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  • 1
    Electronic Resource
    Electronic Resource
    Laser-raman study of crystallinity changes in poly(ethylene terephthalate) (1972)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 10 (1972), S. 317-322 
    Details
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The bandwidth at one-half maximum intensity of the Raman-active C=O stretching vibration was found to correlate with density in poly(ethylene terephthalate). This correlation is valid for unoriented as well as highly oriented materials. It is suggested that a number of rotational states of the terephthalate segment occur in the amorphous polymer. Crystallization causes a resonance-stabilized planar conformation.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1972.160100211
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