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High intrinsic conductivity in ladder type polymers: Pyrolyzed BBB (1990)

Davidov, D. ; Belaish, I. ; Rettori, C. ; [et al.]

New York, NY : Wiley-Blackwell

Polymers for Advanced Technologies 1 (1990), S. 181-188

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ISSN: 1042-7147

Keywords: Chemistry ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics

Notes: Through electrical conductivity and ESR measurements of heat treated BBB-rigid-rod ladder polymers, we provide evidence for the existence of an irreversible transformation to another cross-linked ladder polymer with high intrinsic conductivity. The transformation occurs at a pyrolysis temperature, Tp ≅ 680°C. The results suggest a novel transport mechanism.

Additional Material: 8 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pat.1990.220010207

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