ISSN:
0021-8995
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
The action of metal halides on polyamide (nylon 6) and secondary amide model compounds has been investigated, using infrared and NMR techniques. Metal halides, which are active stress cracking agents for polyamides, induce characteristic changes in the spectra of both nylon 6 and the model compounds. Two types of changes were observed, depending on the metal halide involved, and on this basis the metal halides have been classified as Type I or Type II. The spectral changes appear to be due to the formation of complexes between the amide group and the metal halide, and structures for these complexes are proposed. Type I metal halides, such as zinc, cobaltII, copperII and manganeseII chlorides, form complexes in which the metal atom is coordinately bonded to the carbonyl oxygen atom of the amide group. These agents cause stress cracking by interference with the hydrogen bonding in the polyamide. Type II metal halides, such as lithium, calcium and magnesium chlorides and lithium bromide in solution form proton donating, solvated, species which act as direct solvents for nylon 6 in a manner similar to phenols and formic acid. Type II agents appear to cause simple solvent cracking.
Additional Material:
7 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/app.1969.070130807
