ISSN:
0021-8995
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Dynamic mechanical properties of poly(methyl methacrylate) (PMMA) filled with mica flakes (M) or glass beads (G) were investigated as functions of particle size and filler concentration. With increasing particle size, dynamic modulus E′ slightly decreases for system G, while it increases rapidly at first and then approaches the limiting value for system M. Primary dispersion temperature Tα increases with increasing filler concentration. With increasing particle size, Tα decreases for system G but increases for system M. For the mica-filled system, the effect of particle size on the modulus can be explained in terms of orientation of the filler by comparing the experimental data with Wu's and Padawer and Beecher's predictions of the modulus. In order to explain the dependence of Tα on particle size and concentration, an equation for Tα has been proposed: \documentclass{article}\pagestyle{empty}\begin{document}$ T_\alpha = K_f \ln S^ \cdot $\end{document} where Kf is a constant and S is the specific surface area of filler per gram of polymer. For system G, Tα can be expressed by the above equation, irrespective of particle size and filler concentration. In the case of system M, it is suggested that Tα is affected also by orientation in addition to the surface area of the filler.
Additional Material:
9 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/app.1978.070220513
