ISSN:
0021-8995
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Several poly-1-hexene samples were prepared using different Ziegler-Natta catalysts, and their solubilities in dense carbon dioxide (CO2) were studied. Despite the varied molecular weight distributions (MWD) in the polymers, a surprising correlation was found between intrinsic viscosity and dense CO2 solubility. Due to the ability of dense CO2 to extract low-molecular weight fractions preferentially, it is recommended that narrow MWD polymers be used, as far as possible, for dense CO2 solubility determinations.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/app.1986.070320232