ISSN:
0021-8995
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
The effects of toluene on the kinetics of polymerization of acrylonitrile (AN) initiated by the Ce(IV)/sucrose redox system were studied in the presence of an emulsifier, N-cetyl-trimethylammonium bromide (NCTAB) in the temperature range 35-45°C. The effects of concentration of metal ion, monomer, sulfuric acid, substrate (sucrose), emulsifier, toluene, some inorganic salt, and organic solvent on Rp have also been investigated. The remarkable features of the investigation involve the derivation of the rate expression for the above system with the calculation of activation energy. © 1993 John Wiley & Sons, Inc.
Additional Material:
7 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/app.1993.070490617
