ISSN:
0025-116X
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
Alkyl N-methoxymethylcarbamates (3) were synthesized by treating methoxymethyl isocyanate (1) with alcohols 2 in the presence of triethylamine. By means of 1H NMR spectroscopy and using the deuterated carbamate 3b it could be demonstrated that carbamates 3 undergo decomposition, accompanied by elimination of methanol from the methoxymethylene grouping and by the formation of polycondensates 5. It was found that 1 and 3 react in the presence of basic catalysts to give polyadducts 7.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/macp.1977.021781001