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  • 1
    Electronic Resource
    Electronic Resource
    Polymerizable tautomers, 1. Tautomerism and polymerization of ethyl 3-oxo-4-pentenoate (1986)
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 187 (1986), S. 1087-1095 
    Details
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Solvent effects on the tautomerism and polymerization of ethyl 3-oxo-pentenoate (1) were studied. Regression analysis of the tautomeric constant reveals that the equilibria depend on the polarity and hydrogen-bond donor acidity of the solvents. The polymerization was investigated in benzene and acetonitrile. In both solvents, the kinetic results do not meet the conventional model of radical polymerization.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/macp.1986.021870505
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