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High-pressure phases in polymers. III. The nature of the high-pressure phase in cis-polyisoprene (1976)

Phillips, P. J. ; Edwards, B. C.

New York : Wiley-Blackwell

Journal of Polymer Science: Polymer Physics Edition 14 (1976), S. 377-389

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ISSN: 0098-1273

Keywords: Physics ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: The morphology and growth of the disordered hexagonal phase which crystallizes in films of cis-polyisoprene at pressures in excess of 3 kbar is discussed. A two-stage growth process is proposed consisting of nucleation and crystallization followed by a pressure-enhanced thickening process. The phase is metastable and is replaced by normal spherulitic growth at long times. It transforms into lamellar sheafs with higher than usual lamellar thicknesses when pressure is lowered at constant temperature.

Additional Material: 10 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1976.180140301

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