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Radiation chemistry of linear low-density polyethylene. I. Gel formation and unsaturation effects (1983)

Basheer, Rafil ; Dole, Malcolm

New York : Wiley-Blackwell

Journal of Polymer Science: Polymer Physics Edition 21 (1983), S. 949-956

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ISSN: 0098-1273

Keywords: Physics ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: Quenched and annealed samples of linear low-density polyethylene (LLDPE) were irradiated with 60Co γ rays in vacuo at room temperature. The data follow rather accurately Charlesby's equation s = k/r, where s is the soluble fraction, r the dose, and k a constant from which G(X), the G-value for crosslinks, was calculated. Crosslinking in the LLDPE is about twice as extensive at equal doses as in LHDPE. Production of vinylene unsaturation was approximately the same in the two types of polyethylene.

Additional Material: 4 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1983.180210611

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