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Interpretation of anomalous sorption kinetics in polymer-penetrant systems in terms of a time-dependent solubility coefficient (1984)

Petropoulos, J. H.

New York : Wiley-Blackwell

Journal of Polymer Science: Polymer Physics Edition 22 (1984), S. 1885-1900

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ISSN: 0098-1273

Keywords: Physics ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: A formulation of the molecular relaxation model of anomalous diffusion in polymers, in terms of a time-dependent solubility coefficient, which was previously introduced and studied by us, is discussed here in greater detail. A full account of the methods of application of the treatment is given and the prediction of typical absorption and desorption kinetic features characteristic of glassy polymer-good swelling agent systems, including Case II absorption, is demonstrated.

Additional Material: 9 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1984.180221104

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