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Synthesis of acetylene-terminated polymers using supported palladium (II) catalysts (1987)

Trumbo, D. L. ; Marvel, C. S.

Bognor Regis [u.a.] : Wiley-Blackwell

Journal of Polymer Science Part A: Polymer Chemistry 25 (1987), S. 847-856

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ISSN: 0887-624X

Keywords: Chemistry ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: A polymer-bound palladium catalyst was synthesized from palladium diacetate and a single crystal polyethylene having 2,2′-bipyridyl moieties as pendant groups. The resulting material was used in place of a free palladium catalyst in the synthesis of acetylene-terminated resins. Supports other than polyethylen were also tested for their ability to bind palladium and their subsequent activity as catalysts in the synthesis of acetylene-terminated polymers.

Additional Material: 4 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pola.1987.080250310

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