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Radical polymerization of styrene initiated by styrene-arsenic sulfide complex (1989)

Shukla, Prerna ; Srivastava, A. K.

Bognor Regis [u.a.] : Wiley-Blackwell

Journal of Polymer Science Part A: Polymer Chemistry 27 (1989), S. 3811-3816

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ISSN: 0887-624X

Keywords: Chemistry ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Styrene forms a complex with arsenic sulfide which in DMF at 85°C initiates radical polymerization yielding high molecular weight polymer. The order of reaction, with respect to initiator and monomer, is 0.5 ± 0.02 and unity, respectively. The energy of activation for the system computed as 96 kJ mol-1 and the polymerization is retarded by hydroquinone. A possible mechanism for reaction has also been proposed.

Additional Material: 5 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pola.1989.080271121

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