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Digitale Medien

Hydrosilylation of allyl carbamates by poly(methylhydrosiloxane) and related side-reactions (1993)

Yu, Jian Ming ; Teyssie, Dominique ; Boileau, Sylvie

Bognor Regis [u.a.] : Wiley-Blackwell

Journal of Polymer Science Part A: Polymer Chemistry 31 (1993), S. 2373-2381

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ISSN: 0887-624X

Schlagwort(e): hydrosilylation ; allyl carbamates ; poly(methylhydrosiloxane) ; side-reaction mechanism ; Chemistry ; Polymer and Materials Science

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie

Notizen: Hydrosilylation of allyl carbamates by poly(methylhydrosiloxane) (PMHS) catalyzed by platinum- or rhodium-based complexes was investigated. About 10% of the carbamate molecules decompose during the hydrosilylation reaction through the cleavage of the carbamate bond. A redistribution process also takes place among the polysiloxane chains resulting in the formation of branched polymers but no crosslinking occurs. A mechanism for this side-reaction is proposed. © 1993 John Wiley & Sons, Inc.

Zusätzliches Material: 5 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/pola.1993.080310920

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