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Relative reactivities in vinyl copolymerization (1996)

Alfrey, Turner ; Price, Charles C.

Bognor Regis [u.a.] : Wiley-Blackwell

Journal of Polymer Science Part A: Polymer Chemistry 34 (1996), S. 157-163

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ISSN: 0887-624X

Keywords: Chemistry ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: From data in the literature on relative rates of copolymerization it has been possible to evaluate two constants, Q and e, characteristic of an individual monomer, which appear to account satisfactorily for its behavior in copolymerization. The constant Q describes the “general monomer reactivity” and is apparently related to possibilities for stabilization in a radical adduct. The constant e takes account of polar factors influencing copolymerization.

Additional Material: 5 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pola.1996.807

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