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Polymerization by oxidative coupling. II. Oxidation of 2,6-disubstituted phenols (1996)

Hay, Allan S.

Bognor Regis [u.a.] : Wiley-Blackwell

Journal of Polymer Science Part A: Polymer Chemistry 34 (1996), S. 1373-1383

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ISSN: 0887-624X

Keywords: Chemistry ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Many 2,6-disubstituted phenols are readily oxidized with oxygen, a tertiary amine and a copper (I) salt being used as catalyst. The products are diphenoquinones (I) or 1,4-polyphenylene ethers (II):The effect of variation of the substituents on the phenol and the infrared spectra of the polymers is discussed. Amine complexes of copper salts are the only effective catalysts found for the polymer-forming reaction. The effect on the catalyst of varying the copper salt and the ligand is discussed.

Additional Material: 2 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pola.1996.829

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