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  • 1
    Electronic Resource
    Electronic Resource
    Behavior of semicarbazones under the conditions of the Fischer reaction (1978)
    Springer
    Chemistry of heterocyclic compounds 14 (1978), S. 1208-1210 
    Details
    ISSN: 1573-8353
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Cyclohexanone semicarbazone and phenylsemicarbazone form 1,2,3,4-tetrahydro- and 1,2,3,4,5,6,7,8-octahydrocarbazoles under the conditions of the Fischer reaction. The reaction proceeds through a cyclohexanone azine intermediate. The product of oxidation of the azine is oxidized by air oxygen to 1,2,3,4-tetrahydrocarbazole. The investigated semicarbazones are stable with respect to the action of sodium ethoxide at up to 300°C.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00509738
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