ISSN:
1573-8353
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract A simple preparative method for the synthesis of cis-1-thiahydrindan and cis-2-thiabicyclo[3, 3, 1]nonane has been developed. The method can be used to obtain substituted thiabicyclanes by a general method starting from 3-chloromethylcyclohexene. In the cyclization of 3 (β-mercaptoethyl)cyclohexane both by an ionic and by a radical mechanism, a mixture of cis-1-thiahydrindan and cis-2-thiabicyclo [3,3,1] nonane in approximately equal amounts is formed.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00474874