ISSN:
1573-8353
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The reactions of hexafluoroisobutenylidene sulfate with tertiary amines, ethers, sulfolane, and alkali metal halides were studied. Hexafluorodimethylketene is liberated, and the reagent is sulfotrioxidized during the reaction of hexafluoroisobutenylidene sulfate with these nucleophilic compounds. Hexafluoroisobutenylidene sulfate is an electrophilic compound of the quasicomplex type, which contains a labile sulfotrioxide grouping.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00475279