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Influence of the solvent on the kinetics of the reversible recombination of 2-arylindan-1,3-dionyl radicals (1980)

Yasmenko, A. I. ; Khudyakov, I. V. ; Kuz'min, V. A.

Springer

Russian chemical bulletin 29 (1980), S. 349-353

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ISSN: 1573-9171

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Conclusions 1. On the basis of obtained kinetic and thermodynamic parameters of the reaction of the reversible recombination of the 2-(4′-dimethylaminophenyl)indan-1,3-dionyl radical, it is established that the most dominating influence on the rate of this reaction is nonspecific solvation. 2. Values of rate constants of the recombination of the 2-(4′-diphenylaminophenyl)indan-1,3-dionyl radical has a V-shaped dependence on the parameter ET, Strong solvation of this radical in chloroform converts the recombination reaction from a diffusion-controlled range to a kinetic range.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00949614

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