ISSN:
1573-9171
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Conclusions Trimethylsilyl ethers of the corresponding enols are formed in the gas-phase silylation of aliphatic and alicyclic aldehydes and ketones in a Chromatographic column by N,O-bis(trimethylsilyl)trifluoroacetamide with added Me3SiCl3. The major pathway for the dissociative ionization of these ethers upon electron impact is relative to allylic cleavage.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00953259