ISSN:
1573-9171
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Conclusions 1. The reaction of disproportionation of a geminal radical pair formed in photodissociation of desoxybenzoins is magnetic- and isotope-selective to the same degree as the recombination reaction. 2. The efficiency of separation of12C and13C isotopes based on the magnetic isotope effect decreases in the order desoxybenzoin, α-methyldesoxybenzoin, and α,α-dimethyldesoxybenzoin during photolysis, which is due to an increase in the probability of isotope-selective disproportionation of geminal radical pairs.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00953600