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  • 1
    Electronic Resource
    Electronic Resource
    Correlation between solvent-reorganization dynamics and the kinetics of metallotropy in polar media (1994)
    Springer
    Russian chemical bulletin 43 (1994), S. 368-371 
    Details
    ISSN: 1573-9171
    Keywords: kinetics ; solvent dynamics ; radical
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The kinetics of metallotropy of the 3,6-di-tert-butyl-2-(triphenylstannyl)oxyphenoxyl radical has been studied by ESR. The correlation between chemical exchange time τex, solvent polarity, and longitudinal relaxation time of the solvent corresponds to the model of a process controlled by molecular dynamics. A linear relation between τex and correlation time τc for reorientation movements of the radical is found: τex = α · τc. The coefficient α depends on the dielectric properties of the solvent.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01169707
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