ISSN:
1572-8838
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
,
Electrical Engineering, Measurement and Control Technology
Notes:
Abstract Multistage electrochemical parametric pumping has been successfully carried out for water desalination. Separation was effected by electroadsorption-desorption cycles of the ions into and from the electrical double layer of high surface carbon electrodes. At steady state and total reflux, the concentration ratio between the upper and lower heads of the electrochemical column was as high as 150. Two models for the build up of the concentration profile within the column are presented. The first is based on a solution of the two-phase mass transport equation using the proper boundary and initial conditions. The second treatment is based on the mixed cells assumptions. In both treatments, interphase equilibrium is assumed using the isopotentiograms as the specific equilibrium curves. Use is also made of a fast computer for the simulation of the electrochemical paramatric pumping cycles. The two models are in good agreement with the experimental results particularly in the cases where the initial concentration is high and interphase equilibrium is maintained.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00617523
