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Structural phase transition of Rh2O3 studied via PAC (1990)

Kesten, J. ; Bolse, W. ; Lieb, K. P. ; [et al.]

Springer

Hyperfine interactions 60 (1990), S. 683-686

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ISSN: 1572-9540

Source: Springer Online Journal Archives 1860-2000

Topics: Physics

Notes: Abstract The structural phase transition from α-Rh2O3 to β-Rh2O3 has been studied via the PAC method on dilute111Cd impurity atoms implanted into α-Rh2O3. The measured antishielding factor β=112 (2) in the α-phase is similar to that found for111Cd in other oxides with corundum structure (Al2O3. Cr2O3, Fe2O3). Oxygen with different crystallographic matrices show a pronounced correlation of the electric field gradient with the NN oxygen coordination.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF02399845

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