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Digitale Medien

13-Membered Azocrown Ether. Structure of the Lithium Bromide Complex and Membrane Properties (1998)

Luboch, E. ; Biernat, J. F. ; Kravtsov, V. Ch ; [weitere]

Springer

Journal of inclusion phenomena and macrocyclic chemistry 31 (1998), S. 109-118

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Details

ISSN: 1573-1111

Schlagwort(e): azocrown ether ; lithium complex ; X-ray structure ; membrane electrodes

Quelle: Springer Online Journal Archives 1860-2000

Thema: Chemie und Pharmazie

Notizen: Abstract The lithium bromide hydrate complex ofthe 13-membered dibenzoazocrown ether of composition{[LiL13(H2O)]Br}2 has been synthesized. Its structure has been determined by the X-ray method. Thecrystals are monoclinic, space group C2/c, a =12.720(6), b = 19.969(9), c = 13.963(6)Å; β = 104.32(2)°. Selectivities of membraneelectrodes based on 13-membered azocrown ethers arediscussed in terms of complex stabilities and metalcation extractabilities as related to the structuresof the respective complexes.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1023/A:1007940713524

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