ISSN:
1573-4803
Source:
Springer Online Journal Archives 1860-2000
Topics:
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
Notes:
Abstract The wettability and the adhesion of polyethylene films were improved by introducing polar groups in the polymer chains. The surface properties of films grafted with maleic anhydride (MA) were investigated. The wettability was found to be dependent on the MA content, on the film preparation conditions and on the hydrolytic process of the anhydride groups. The kinetics of the hydrolysis indicated a restructuring of the polymeric surface due to the movement of the polar groups towards the surface; it did not influence the adhesion properties. The behaviour of the maleinized films was compared with oxygen plasma treated materials, which showed a better wettability, but a worse adhesion on polar substrates than the maleinized polyethylene. These results were explained on the basis of X-ray photoelectron spectroscopic analyses, by which the main functional groups present at the surface were identified and quantitatively determined. © 1998 Chapman & Hall
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1004391524045