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On the generation mechanism of aromatic cation-radicals under adsorption on zeolites (1992)

Yudanov, I. V. ; Zakharov, I. I. ; Zhidomirov, G. M.

Springer

Reaction kinetics and catalysis letters 48 (1992), S. 411-417

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ISSN: 1588-2837

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Description / Table of Contents: Abstract На основе неэмпирических квантовохимических расчетов предложена молекулярная модель адсорбции кислорода на льюисовском кислотном центре цеолита. Сделано предположение о том, что такой адсорбционный комплекс способен выступать в качестве акцептора электрона в процессе образования катион-радикалов бензола.

Notes: Abstract Nonempirical quantum-chemical calculations suggest a molecular model for oxygen adsorption on Lewis acid sites of zeolites. This adsorption complex is assumed to be capable of acting as an electron acceptor in the generation of benzene cation-radicals.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF02162689

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