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Pressure effects on the Raman spectra of 3-deutero-ammonia, lattica dynamics and vibrons up to 40 GPa (1990)

Pruzan, Ph. ; Gauthier, M. ; Chervin, J. C.

Springer

International journal of thermophysics 11 (1990), S. 259-267

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ISSN: 1572-9567

Keywords: ammonia ; deutero-ammonia ; high pressure ; hydrogen bond ; Raman spectra

Source: Springer Online Journal Archives 1860-2000

Topics: Physics

Notes: Abstract High-pressure Raman studies up to 40 GPa have been made on solid ND3 at room temperature. Features of external and internal modes are compared to that of solid NH3 and mode assignments are proposed in solid phase IV (p⩽3.8 GPa). In contrast with NH3, which transforms to a cubie phase at 15 GPa, solid IV ND3 was observed to be stable up to 40 GPa, the upper limit of the present investigation. It is concluded that bond symmetrization in ND3 will occur above that of NH3.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00503876

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