ISSN:
1432-2234
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The contributions of the spin-dipolar and orbital terms to the nuclear spin coupling constants $$J_{13_C - 13_C }$$ in acetylene, ethylene and ethane have been evaluated by systematically using the Mulliken-Ruedenberg approximation for the matrix elements of the corresponding operators. Both contributions are found to be negligeable as compared to the usual contact term.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00529094