ISSN:
1432-2021
Quelle:
Springer Online Journal Archives 1860-2000
Thema:
Chemie und Pharmazie
,
Geologie und Paläontologie
,
Physik
Notizen:
Abstract Dislocation configurations in natural single crystals of CaTiO3 perovskite deformed in high-temperature creep were examined and characterized by transmission electron microscopy. Screw dislocations with Burgers vector [100]pc and [011]pc, dissociated on the $$(01\bar 1)_{{\text{pc}}} $$ plane, form rectangular networks with extended four-fold nodes in the shape of octagons, a configuration never observed in any of the previously investigated perovskites, except CaGeO3. Screw dislocations with Burgers vector [101]pc and $$(\bar 101)_{{\text{pc}}} $$ , on the (010)pc plane, react to form a twist wall; the dislocations with Burgers vector [002] produced by the reaction decompose into two perfect dislocations [001]pc. This results in a new configuration, never observed before, with three-fold nodes at the corners of rectangles. Both the octagonal extended nodes and the junctions decomposed into perfect dislocations are seen in samples deformed indifferently by slip on {100}pc or {110}pc planes, but they seem to appear only above 1520 K, in the cubic phase.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1007/BF00199499
