ISSN:
1435-1528
Keywords:
Rheology
;
liquid crystal
;
monodomain
;
instability
;
conoscopy
;
shear
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
Abstract We have measured the shear-induced rotation of the nematic director in a liquid crystalline polymer using poly benzyl glutamate (PBG) as model system. PBG is a well characterized synthetic poly (α amino acid) with rigid chain architecture and well defined conformations. For the experiments it is important to start out with a sample in which the molecules are highly aligned with a uniform director. This so-called monodomain morphology is obtained by use of strong magnetic fields and surface modifications of the sample holders. When shearing the monodomain at a constant rate, the macromolecules rotate initially homogeneously until a periodic director pattern develops. These spatially periodic structures emerge in a narrow range of shear strain and, as shearing continues, disintegrate into a chaotic texture. By varying the initial monodomain director with respect to the flow direction (but within the shear planes) we could show that the periodic patterns do not depend on the shear direction; they are governed by the director of the initial monodomain. We observe conoscopically that at high shear rates the texture becomes uniformly aligned. The molecules are aligned preferentially with an angle of about 4° to the shear direction (against vorticity direction). Interestingly, this agrees very well with predictions made by Larson (1990).
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00396043
