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Darstellung und Reaktionenvon Oxidationsprodukten aus β-Campholenverbindungen (1999)

Wyßuwa, Kerstin ; Anhalt, Katrin ; Schulze, Klaus

Springer

Monatshefte für Chemie 130 (1999), S. 809-817

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ISSN: 1434-4475

Keywords: Keywords. β-Campholenic compounds; Epoxidation; KMnO4 oxidation; Reduction of epoxides; Allylic alcohols.

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Summary. Whereas the synthesis of α-campholenic compounds starting from α-pinene has been well investigated, only few is known about β-campholenic compounds. We obtained compounds suitable as precursors for the functionalization of the side chain of the β-isomer of the sandalwood flavour Brahmanol®. Now we report about the synthesis and the rearrangement of various β-campholenic epoxides to allylic alcohols or a bicyclic γ-lactone and the synthesis of cyclohexenones from β-campholenic esters.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/PL00010262

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