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  • 1
    Electronic Resource
    Electronic Resource
    Mechanism of the oxidation of cycloheptanone by chloramine-T (1975)
    Springer
    Monatshefte für Chemie 106 (1975), S. 863-869 
    Details
    ISSN: 1434-4475
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The oxidation kinetics of cycloheptanone by chloramine-T in alkaline media has been investigated. A mechanism involving the formation of an intermediate by the interaction between the enolic anion of cycloheptanone and chloramine-T in a slow step followed by its interaction with another molecule of chloramine-T in a fast step leading to products has been proposed. The scheme satisfactorily accords with the observed stoichiometry, negligible influence of ionic strength and a positive dielectric effect. Various rate parameters have been computed and 1.2-cycloheptanedione identified as the end product.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00900865
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